Kinetic study of uracil tautomerization in the gas phase

In this research the kinetics and thermodynamic of reaction of uracil tautomers in gas phase have been studied. Hydrogen transfer from Lactam to produce lactim is carried out R۱. In R۲ reaction there is also a hydrogen abstraction. Reaction scheme is shown below:(...)Uracil is one of the four nucleobases in the nucleic acid of RNA. It is a common and naturally occurring pyrimidine derivative. This tautomers is the hydrogen bond acceptor and can form two hydrogen bonds.

کلیدواژه ها:

Kinetics ، Potential Energy Surface ، Rate Constant ، Tautomerization.