GREEN SYNTHESIS AND CHARACTERISATION OF COPPER OXIDE NANOPARTICLES - REDUCED GRAPHENE OXIDE NANO COMPOSITES FOR FACILE ELECTROCHEMICAL OXIDATION OF PONCEAU ۴R AND ALIZARIN RED DYES IN AQUEOUS MEDIUM

Copper oxide nanoparticles are prepared adopting green synthesis route by using Aloe vera plant extract instead of synthetic and polymeric stabilizing agents in mild alkaline aqueous conditions. The synthesised CuO nanoparticles (CuO nps) are characterised by Powder XRD and HR-TEM measurements. Using the as –synthesized CuO nps and reduced graphene oxide (rGO), nanocomposites comprising CuO nps- rGO are prepared by hydrothermal and ultrasonic methods. Nano composites are characterized using Powder XRD, HR-TEM and FE-SEM data. The fabricated CuO nps - rGO nanocomposites are coated onto glassy carbon electrode (GCE) for facile detection and electro oxidation of water polluting dyes such as the Ponceau ۴R (P۴R) and Alizarin Red (AR) using cyclic voltammetry . Electro oxidation of the dyes occurred at appreciably lower oxidation potentials like ۰.۴۵ V and ۰.۶ V for P۴R and AR respectively along with the decoloration of the dyes. The absorbance of the analyte dye solutions are measured at intervals of time of progress of electro oxidations. The overall first order rate coefficient values for dye degradations are found out from absorbance time variance data. The results indicate that CuO nps - rGO nanocomposites decorated GCE acted as an efficient electrode surface for sensing and degradation applications for the chosen dye solutions. P۴R azo dye degradation response was found to be better than AR anthroquinon dyes.

کلیدواژه ها:

CuO nanoparticles ، reduced graphene oxide nanocomposites ، Electrochemical oxidation of Ponceau ۴R and Alizarin Red