Theoretical Electrochemical Study and Free Energies of Electron Transfer of Norepinephrine (ne) With Fullerenes in (n= 60, 70, 76, 82 and 86)

Neurotransmitters are the chemicals which allow the transmission of signals from one neuron to the next acrosssynapses. They are also found at the axon endings of motor neurons, where they stimulate the muscle fibers. And theyand their close relatives are produced by some glands such as the pituitary and the adrenal glands. In this study, thenumber of carbon atoms in fullerenes was used as descriptors to establish a good relationship between the structure ofNorepinephrine and Fullerenes Cn (n= 60, 70, 76, 82 and 86). The first to forth free activation energies of electrontransfer and kinetic rate constant of the electron transfer, ΔG#et(n) and ket(n), λet(n) n=1-4 , respectively werecalculated in this study for Norepinephrine with Fulleren Cn complexes with used calculated of four free energies ofelectron transfer ΔG#et(n) (ΔG#et(1) to ΔG#et(4) of this supramolecular complexes. This calculation are agree withthe Marcus theory.

کلیدواژه ها:

Norepinephrine ، Fulleren ، Marcus theory