Synthesis, Characterization and Catalytic Properties of GO@Fucoidan: A Heterogeneous Bio-Based Catalyst for the Synthesis of α-aminophosphonate Derivatives
محل انتشار: دومین کنفرانس کاتالیست انجمن شیمی ایران
سال انتشار: 1398
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 268
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شناسه ملی سند علمی:
ICCO02_170
تاریخ نمایه سازی: 3 اردیبهشت 1399
چکیده مقاله:
In this study, Fucoidan (FU), a fucose-rich sulfated polysaccharide extracted from brown algae Fucus vesiculosus was used for preparation of GO@FU composites. The structural and properties of GO@FU were investigated by EDX, XRD, FT-IR, TGA, SEM, The catalytic activity of GO@FU was studied for the synthesis of α-aminophosphonates through three-component reactions aldehydes/ ketones, amines and nucleophile such as triethyl phosphite. Easy ways of synthesis, high product yield and short reaction time made GO@FU an attractive and efficient heterogeneous biocatalyst for organic chemist.
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نویسندگان
Sara Amirnejat
Heterocyclic Chemistry Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran ۱۶۸۴۶-۱۳۱۱۴, Iran
Aliakbar Nosrati
Heterocyclic Chemistry Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran ۱۶۸۴۶-۱۳۱۱۴, Iran
Shahrzad Javanshir
Heterocyclic Chemistry Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran ۱۶۸۴۶-۱۳۱۱۴, Iran