Highly selective removal of Pb(II) ions using one-pot thiol- functionalized nanoporous silica with a low amount of directing agent
- سال انتشار: 1399
- محل انتشار: مجله بین المللی فناوری نانو در آب و محیط زیست، دوره: 5، شماره: 4
- کد COI اختصاصی: JR_JWENT-5-4_003
- زبان مقاله: انگلیسی
- تعداد مشاهده: 263
نویسندگان
Kish International Campus, University of Tehran, Kish, Iran
School of Chemistry, College of Science, University of Tehran, Tehran, Iran
School of Chemistry, College of Science, University of Tehran, Tehran, Iran
School of Chemistry, College of Science, University of Tehran, Tehran, Iran
چکیده
In this study, thiol-functionalized nanostructure silica type MCM-۴۱ was successfully prepared via the facile one-pot hydrothermal method with low amounts of the directing agent. The mesoporous silica indicated a remarkable adsorption behavior toward Pb(II) ions without any interference of the competing ions. The main experimental variables affecting removal efficiency of the adsorbent were examined, and the optimized conditions were achieved as to be ۶, ۵۰ mg, and ۳۰ min for solution pH, the adsorbent dosage, and contact time, respectively. The adsorbent was triumphantly used for the removal of Pb (II) ion from real water samples with a notable removal efficiency as ۹۵%. The concentrations of the competitive ions in the solution were about ۱۰ to ۱۰۰ times more than Pb (II) ions. The results show that other ions had no interfering effect on the removal efficiency of Pb (II) ions. It means that SH-SiO۲ has excellent selectivity for Pb (II) ions and is an appropriate candidate for removing Pb (II) ions from the real samples.کلیدواژه ها
adsorbent, Thiol- mesoporous silica, Pb (II) ionsاطلاعات بیشتر در مورد COI
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