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Covalently Bonded PIDA on SBA-15: A versatile new support for the synthesis of Palladium pre-catalyst

عنوان مقاله: Covalently Bonded PIDA on SBA-15: A versatile new support for the synthesis of Palladium pre-catalyst
شناسه ملی مقاله: ISOC27_326
منتشر شده در بیست و هفتمین کنفرانس شیمی آلی ایران در سال 1398
مشخصات نویسندگان مقاله:

Saeed Ghasemi Laki - Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.
Hassan Alamgholiloo - Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran
Sadegh Rostamnia - Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.
Esmail Doustkhah - Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.

خلاصه مقاله:
Very recently, design of a heterogeneous catalyst with higher efficiency has been directed towards the development of stable supporting ligands, complexes and other catalytic species onto nanostructured materials 1, 2. Among nanostructured materials, silica mesoporous materials (SBA-15) owing to their higher stability and surface area are most popular for such purposes 3. I this study, we functionalized its analogue N-propyliminodiacetic acid (PIDA) onto SBA-15 (SBA-15/PIDA) as support of PdII ions to generate a PdII@SBA-15/PIDA catalyst Figure 1. Finally, performance catalytic PdII@SBA-15/PIDA was subsequently investigated in the Suzuki reaction with excellent conversion.

کلمات کلیدی:
SBA-15, Suzuki reaction, Pd@SBA-15/PIDA, Heterogeneous catalyst

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/1164104/