Covalently Bonded PIDA on SBA-15: A versatile new support for the synthesis of Palladium pre-catalyst

سال انتشار: 1398
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 177

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شناسه ملی سند علمی:

ISOC27_326

تاریخ نمایه سازی: 19 اسفند 1399

چکیده مقاله:

Very recently, design of a heterogeneous catalyst with higher efficiency has been directed towards the development of stable supporting ligands, complexes and other catalytic species onto nanostructured materials 1, 2. Among nanostructured materials, silica mesoporous materials (SBA-15) owing to their higher stability and surface area are most popular for such purposes 3. I this study, we functionalized its analogue N-propyliminodiacetic acid (PIDA) onto SBA-15 (SBA-15/PIDA) as support of PdII ions to generate a PdII@SBA-15/PIDA catalyst Figure 1. Finally, performance catalytic PdII@SBA-15/PIDA was subsequently investigated in the Suzuki reaction with excellent conversion.

نویسندگان

Saeed Ghasemi Laki

Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.

Hassan Alamgholiloo

Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.Department of Organic Chemistry, Faculty of Chemistry, Urmia University, Urmia, Iran

Sadegh Rostamnia

Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.

Esmail Doustkhah

Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, PO Box ۵۵۱۸۱-۸۳۱۱۱.