The Bis(4-methoxy-2-hydroxybenzophenone) copper(II) Complex Used as a New Precursor for Preparation of CuO Nanoparticles
- سال انتشار: 1398
- محل انتشار: نشریه متدهای شیمیایی، دوره: 4، شماره: 2
- کد COI اختصاصی: JR_CHM-4-2_004
- زبان مقاله: انگلیسی
- تعداد مشاهده: 426
نویسندگان
Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran
Department of Chemistry, Payame Noor University, PO Box ۱۹۳۹۵-۳۶۹۷ Tehran, Iran
Institute of Physic of the Czech Academy of Sciences, Na Slovance ۲, ۱۸۲ ۲۱ Prague, Czech Republic
Institute of Physic of the Czech Academy of Sciences, Na Slovance ۲, ۱۸۲ ۲۱ Prague, Czech Republic
چکیده
In this study, the reaction of 4-methoxy-2-hydroxybenzophenone (HL) with copper(II) nitrate three hydrate in a 1:2 molar ratio in methanol as solvent resulted in the formation of the complex CuL2. In order to prepare a suitable single crystal, slow evaporation technique was used, while for preparing complex nanoparticles, assisted ultrasound was used. Crystal structure of CuL2 was determined by single crystal X-ray diffraction. A square-planar geometry was found for CuL2. Finally, the complex was calcinated at 600 °C for 2.5 h. The final residue was CuO nanoparticles which were characterized by SEM and XRD. There is no peak for impurity in the XRD pattern. In this study, the reaction of 4-methoxy-2-hydroxybenzophenone (HL) with copper(II) nitrate three hydrate in a 1:2 molar ratio in methanol as solvent resulted in the formation of the complex CuL2. In order to prepare a suitable single crystal, slow evaporation technique was used, while for preparing complex nanoparticles, assisted ultrasound was used. Crystal structure of CuL2 was determined by single crystal X-ray diffraction. A square-planar geometry was found for CuL2. Finally, the complex was calcinated at 600 °C for 2.5 h. The final residue was CuO nanoparticles which were characterized by SEM and XRD. There is no peak for impurity in the XRD pattern.کلیدواژه ها
Copper(II) complex, Square-planar geometry, X-ray diffraction, CuO nanoparticlesاطلاعات بیشتر در مورد COI
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