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Preparation of Ni catalysts on Al-HMS nanostructure support via supercritical deposition in supercritical carbon dioxide–methanol solution with thermodynamic control of metal loading

عنوان مقاله: Preparation of Ni catalysts on Al-HMS nanostructure support via supercritical deposition in supercritical carbon dioxide–methanol solution with thermodynamic control of metal loading
شناسه ملی مقاله: CNS02_086
منتشر شده در دومین کنفرانس نانوساختارها در سال 1386
مشخصات نویسندگان مقاله:

M Alibouri - Catalysis Research Center, Research Institute of Petroleum Industry
S.M Ghoreishi - Department of Chemical Engineering
H.R Aghabozorg - Catalysis Research Center, Research Institute of Petroleum Industry
A Fazlollahi - Catalysis Research Center, Research Institute of Petroleum Industry

خلاصه مقاله:
Preparation of Ni/Al-HMS (Hexagonal Meso Structured) catalysts by the supercritical deposition method was investigated. Metal loading can be controlled thermodynamically based on the adsorption isotherm of the metal salts between the supercritical carbon dioxide-methanol phase and the Al-HMS phase. In this route, Al-HMS was impregnated with Ni(NO3)2 . 6H2O that dissolved in supercritical CO2–methanol solution and the resulting composites were converted to Ni/Al-HMS catalysts. Methanol as cosolvent enhanced the dissolution of precursors in supercritical CO2.

کلمات کلیدی:
Supercritical Deposition; Nanocomposite; HMS; Catalyst

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/91705/