Defect Engineering of a Chromium-Based Metal–Organic Framework for Catalysis

سال انتشار: 1397
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 346

نسخه کامل این مقاله ارائه نشده است و در دسترس نمی باشد

استخراج به نرم افزارهای پژوهشی:

لینک ثابت به این مقاله:

شناسه ملی سند علمی:

ISOC26_196

تاریخ نمایه سازی: 2 شهریور 1398

چکیده مقاله:

MIL-101(Cr), one of the most robust and stable MOFs, is widely used in many scientificfields [1,2]. The presence and nature of structural defects of the MIL-101(Cr)-NO2 has beenrecognized as a key factor shaping the material’s physical and chemical behavior. In thiswork, the formation of the missing linker defects have been investigated for the Prins couplingof β-pinene and formaldehyde as shown in the Fig. 1. The results indicate that the defectshave a significant impact on Lewis and Brønsted acidity of the MOF.

نویسندگان

Saba Daliran

Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran

Ali Reza Oveisi

Department of Chemistry, Faculty of Science, University of Zabol, Zabol, Iran