Molecular Structure, NMR, FMO, MEP and NBO Analysis of Ethyl-(Z)-3-phenyl-2-(5-phenyl-2H-1,2,3,4-tetraazol-2-yl)-2-propenoate Based on HF and DFT Calculations
- سال انتشار: 1396
- محل انتشار: نشریه متدهای شیمیایی، دوره: 1، شماره: 1
- کد COI اختصاصی: JR_CHM-1-1_003
- زبان مقاله: انگلیسی
- تعداد مشاهده: 376
نویسندگان
Department of Chemistry, University of Zanjan, P O Box ۴۵۱۹۵-۳۱۳, Zanjan, Iran
Young Researchers and Elite Club, Gorgan Branch, Islamic Azad University, Gorgan, Iran
Department of Chemistry, Zanjan Branch, Islamic Azad University, Zanjan, Iran
چکیده
In the present work, for the first time the quantum calculations of Ethyl-(Z)-3-phenyl-2-(5-phenyl-2H-1,2,3,4-tetraazol-2-yl)-2-propenoate are evaluated using the HF and B3LYP methods with 6-311++G** basis set. The geometry of the title compound was optimized by B3LYP/6-311++G** level of theory. The theoretical 1H and 13C NMR chemical shift values of the title compound are calculated and compared with the experimental results. The computed data are in good agreement with the experimental data. Frontier molecular orbitals (FMOs), molecular electrostatic potential (MEP), energy gap between HOMO and LUMO, electronic properties, thermodynamic parameters, natural charges distribution (NBO charges) and NBO analysis were investigated by theoretical calculations. In the present work, for the first time the quantum calculations of Ethyl-(Z)-3-phenyl-2-(5-phenyl-2H-1,2,3,4-tetraazol-2-yl)-2-propenoate are evaluated using the HF and B3LYP methods with 6-311++G** basis set. The geometry of the title compound was optimized by B3LYP/6-311++G** level of theory. The theoretical 1H and 13C NMR chemical shift values of the title compound are calculated and compared with the experimental results. The computed data are in good agreement with the experimental data. Frontier molecular orbitals (FMOs), molecular electrostatic potential (MEP), energy gap between HOMO and LUMO, electronic properties, thermodynamic parameters, natural charges distribution (NBO charges) and NBO analysis were investigated by theoretical calculations.کلیدواژه ها
Ttetrazole, DFT, Natural charge, NBO analysis, Electronic propertiesاطلاعات بیشتر در مورد COI
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