Investigation of performances of solvents D2EHPA, Cyanex272, and their mixture system in separation of some rare earth elements from a Nitric Acid solution

  • سال انتشار: 1395
  • محل انتشار: مجله معدن و محیط زیست، دوره: 7، شماره: 2
  • کد COI اختصاصی: JR_JMAE-7-2_001
  • زبان مقاله: انگلیسی
  • تعداد مشاهده: 240
دانلود فایل این مقاله

نویسندگان

Seyyed M. Seyyed Alizadeh Ganji

School of Mining, Petroleum & Geophysics Engineering, Shahrood University of Technology, Shahrood, Iran

S. Z. Shafaie

School of Mining Engineering, College of Engineering, University of Tehran, Tehran, Iran

N. Goudarzi

Faculty of Chemistry, Shahrood University of Technology, Shahrood, Iran

چکیده

This work was aimed to evaluate and compare the performances of the solvents D2EHPA (Di-(2-ethylhexyl) phosphoric acid), Cyanex 272 (bis (2,4,4-trimethylpentyl) phosphinic acid), and a mixture system of D2EHPA and Cyanex272 in the separation of some rare earth elements (REEs) including lanthanum, gadolinium, neodymium, and dyspersym from a nitric acid solution. The results obtained showed that Cyane272 had the lowest separation factor in the separation of Dy, La, Nd, and Gd from each other. Also it was found that a mixture system of D2EHPA and Cyanex272 had the best performance in the separation of the investigated REEs, owing to the higher separation factors for Dy/Nd and Dy/Gd, as well as the lower extraction efficiencies for Gd (64.54%), La (30.07%), and Nd (26.47) from Dy (99.92). It was also determined that the separation factors forDy/Nd and Dy/Gd were 720.05 and 3640.27, respectively, using their mixture system.

کلیدواژه ها

Rare Earth Elements (REEs), Separation Factor, D2EHPA, Cyanex272, Mixture System

اطلاعات بیشتر در مورد COI

COI مخفف عبارت CIVILICA Object Identifier به معنی شناسه سیویلیکا برای اسناد است. COI کدی است که مطابق محل انتشار، به مقالات کنفرانسها و ژورنالهای داخل کشور به هنگام نمایه سازی بر روی پایگاه استنادی سیویلیکا اختصاص می یابد.

کد COI به مفهوم کد ملی اسناد نمایه شده در سیویلیکا است و کدی یکتا و ثابت است و به همین دلیل همواره قابلیت استناد و پیگیری دارد.