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Introduction of benzimidazole-based ionic liquid as an efficient and reusable catalyst for the preparation of 1,8-dioxo xanthene derivatives

عنوان مقاله: Introduction of benzimidazole-based ionic liquid as an efficient and reusable catalyst for the preparation of 1,8-dioxo xanthene derivatives
شناسه ملی مقاله: IRANCC20_229
منتشر شده در بیستمین کنگره شیمی ایران در سال 1397
مشخصات نویسندگان مقاله:

Bahareh Abbas khakiani - Department of Chemistry, College of Science, University of Guilan, Rasht, Iran
Nader Daneshvar - Department of Chemistry, University campus ۲, University of Guilan, Rasht, Iran
Hasan Tajik - Department of Chemistry, University campus ۲, University of Guilan, Rasht, Iran
Farhad Shirini - Department of Chemistry, College of Science, University of Guilan, Rasht, Iran,Department of Chemistry, University campus ۲, University of Guilan, Rasht, Iran

خلاصه مقاله:
Xanthenes are biologically important drug intermediates for the synthesis of compounds having antibacterial, anti-inflammatory and antiviral activities [1]. Also,they were used as dyes in laser technologies, and in fluorescent materials for visualization of biomolecules. Because of these significant features there has been a continuous interest in the synthesis of these types of compounds and consequently numerous approaches have been reported for their synthesis [2]. Ionic liquids have received considerable interest as eco-friendly solvents, catalysts and reagents in organic synthesis because of their unique properties, such as low volatility, non-flammability, high thermal stability, negligible vapor pressure and ability to dissolve a wide range of materials [3]. In this work, a dicationic ionic liquid based on benzimidazole is simply prepared andafter is used for the promotion of the synthesis of 1,8-dioxoxanthene derivatives. The main advantage for using this catalyst are ease of separation of the catalyst, highyields of achived products during low reaction times.

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/850863/