The Synthesis and characterization of 4-(2-(3-chloro-2-hydroxypropyl)-2H-tetrazol-5-yl-2-methoxyphenol
محل انتشار: همایش منطقه ای شیمی
سال انتشار: 1389
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 260
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شناسه ملی سند علمی:
MIAUCHEMISTRY01_075
تاریخ نمایه سازی: 18 اسفند 1397
چکیده مقاله:
In recent years a new research field has been developed in the tetrazole chemistry, coordination complexes containing a tetra- zole group have been the subject of an intense research effort due to their variety of intriguing architectures and their potential applications in advanced materials 1]. In this research work, we synthesized some new compounds of alkyl tetrazoles. Therefore, 4-hydroxy-3-methoxybenzaldehyd (1) in reaction with NH2OH was converted to 4-hydroxy-3-methoxybenzaldehyde oxime (2). The obtained compound was dehydrated by acetic anhydride to give 4-hydroxy-3-methoxybenzonitrile (3). Then, 2-methoxy-4-(2H-tetrazol-5-yl)phenol(4) was prepared by [2+3] cycloaddition reaction between (3) and NaN3.Compound 4-(2-(3-chloro-2-hydroxypropyl)-2H-tetrazol-5-yl-2-methoxyphenol (5) produced from the reaction of compound (4) with epyclorohydrine. The structure of all the synthesized compounds were characterized and confirmed by FT-IR and NMR spectroscopy techniques.
نویسندگان
Ladan Edjlali
Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
M Babazadeh
Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
G. Nikfar
Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran
Y Soleymani
Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Tabriz Branch, P.O.Box ۱۶۵۵, Tabriz, Iran