Single walled carbon nanotube in the reaction layer for oxygen reduction reaction in gas diffusion electrodes

سال انتشار: 1393
نوع سند: مقاله ژورنالی
زبان: انگلیسی
مشاهده: 333

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شناسه ملی سند علمی:

JR_IJHFC-1-2_002

تاریخ نمایه سازی: 21 فروردین 1397

چکیده مقاله:

In this paper, the effect of surface area in the reaction layers of gas diffusion electrodes for oxygen reduction reaction (ORR) was investigated. Various amounts (0, 0.1, 0.2, 0.3, 0.4, 0.5, 1 and 1.5%wt of reaction layer) of single walled carbon nanotube (SWCNT) were inserted in the reaction layer. The results were studied in a three-electrode half-cell system configuration, which connected to a potentiostatgalvanostat system via linear sweep voltammetry (LSV), cyclic voltammetry (CV), chronoamperometry (CHA) and impedance analysis. The results indicated that the addition of SWCNT, by changing in surface area of catalyst layer can improve the ORR kinetics parameters. The best performance is obtained for an electrode with 0.4% SWCNT

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نویسندگان

Rasol Abdullah Mirzaie

Fuel Cell Research Laboratory, Department of Chemistry, Faculty of Science, Shahid Rajaee Teacher Training University, Tehran, Iran

Rahil Yazdanshenas

Fuel Cell Research Laboratory, Department of Chemistry, Faculty of Science, Shahid Rajaee Teacher Training University, Tehran, Iran

Ahmad Nozad Golikand

Material Research Center, Isfahan, Iran

Mehdi Kheirmand

Department of Chemistry, Faculty of Science, Yasouj University, Yasouj, Iran