A Thermodynamic Study on the Cationic Ring-Opening Polymerization of Tetrahydrofuran
عنوان مقاله: A Thermodynamic Study on the Cationic Ring-Opening Polymerization of Tetrahydrofuran
شناسه ملی مقاله: ISPST10_815
منتشر شده در دهمین سمینار بین المللی علوم و تکنولوژی پلیمر در سال 1391
شناسه ملی مقاله: ISPST10_815
منتشر شده در دهمین سمینار بین المللی علوم و تکنولوژی پلیمر در سال 1391
مشخصات نویسندگان مقاله:
Reza Jahanmardi - Department of Polymer Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran
Faramarz Afshar-Taromi - Department of Polymer Engineering, Amir Kabir University of Technology,Tehran, Iran
Saeed Pourmahdian - Department of Polymer Engineering, Amir Kabir University of Technology,Tehran, Iran
خلاصه مقاله:
Reza Jahanmardi - Department of Polymer Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran
Faramarz Afshar-Taromi - Department of Polymer Engineering, Amir Kabir University of Technology,Tehran, Iran
Saeed Pourmahdian - Department of Polymer Engineering, Amir Kabir University of Technology,Tehran, Iran
Polymerization of tetrahydrofuran (THF) is one of the widely studied cationic ring opening polymerizations [1]. The products of THF polymerization are commercially used asmediate materials for polyurethane and polyester elasomers. Since the original report of THF polymerization by Meerwein in the late 1930 s, various types of compounds have been reported as initiators [2]. However, only a few systems are suitable for preparing polymer of narrow molecular weightdistribution in high conversion with good molecular weight control. One of these systems is perchloric acid (HClO4)-acetic anhydride (Ac2O) mixture which has been used in commercial production of poly(tetrahydrofuran) (PTHF) in some cases [3]. Although, there is much information aboutmechanistic features of THF polymerization in this particular system, there is a few thermodynamic data for it. In this article, we report the results of thermodynamic study of THF polymerization initiated by HClO4- Ac2O mixture
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/580172/