M. Ghasemi - Faculty of chemistry, Semnan university, Semnan, Iran
E. Kosari - Department of Chemistry, Amirkabir University of Technology, Tehran, Iran
A. Amoozadeh - Department of Chemistry, Amirkabir University of Technology, Tehran, Iran

Polyamide-imide (PAI) is a high performance condensation polymer, which has high heat and radiation resistance. Solvent suspension of PAI are widely used in magnetic wire coatings. In present study a PAI based on amino acid, was synthesized via direct polycondensation of a synthesized diacid-diimide and 4,4-(1,4-Phenylenediisopropylidene) bisaniline (PDBA). Diacidediimide was synthesized by the condensation of an amino acid compound, (S)-(+)-Histidine hydrochloride monohydrate and 3,3_,4,4_-Benzophenone tetracarboxylic dianhydride (BTDA). The mentioned monomer was characterized by FT-IR, 1H-NM R and 13C-NMR spectroscopies. Thermal stability of PAI was studied using thermogravimetric analysis (TGA). Morphology of the PAI was studied before and after the biodegradation by scanning electron microscopy (SEM) technique. The in vitro fungal col onization of diacid monomer and PAI were tested using Aspergillus niger fungi. After biodegradation, the monomer showed a weight loss of 8.2 wt % and synthesized PAI also showed lower weight losses rather than the monomer.

Biodegradable- Poly (amide-imide)- Fungal colonization- Coating- Histidine