The effect of influent concentration on the breakthrough curve of zinc sorption by magnetic nanocomposite in a fixed-bed column

  • سال انتشار: 1393
  • محل انتشار: پانزدهمین کنگره ملی مهندسی شیمی ایران
  • کد COI اختصاصی: ICHEC15_112
  • زبان مقاله: انگلیسی
  • تعداد مشاهده: 885
دانلود فایل این مقاله

نویسندگان

Shokokoofeh Ghasemi

School of Chemical, Gas and Petroleum Engineering, Semnan University, Semnan, Iran

Siavash Mansouri

Faculty of Chemical Engineering, Babol University of Technology, Babol, Iran

Mohsen Mehdipour Ghazi

School of Chemical, Gas and Petroleum Engineering, Semnan University, Semnan, Iran

Mohsen ghorbani

Faculty of Chemical Engineering, Babol University of Technology, Babol, Iran

چکیده

In the present study, maghemite (γ−Fe2O3) nanoparticles were synthesized in one step by co-precipitation method and then coated by polyrhodanine via chemical oxidation polymerization. The prepared magnetic nanocomposite was used as an effective adsorbent to separate zinc ions from aqueous solution in a fixed-bed column. The effect of influent Zn concentration on the breakthrough characteristics of the adsorption system was determined. Various initial Zn concentrations from 50 to 150mg/L were used. The breakthrough time, exhausted time and treated volume decreased with the increase of influent concentration. The maximum percentage of Zn adsorption on γ−Fe2O3/polyrhodanine nanocomposite was 59.5% at 50mgL-1 influent concentration of Zn ions. The amount of maximum adsorption capacity increased from 20.59mg/g to 33.6mg/g with increasing influent concentration from 50mg/L to 150mg/L. The increase of maximum capacity with increasing of initial Zn concentration may be due to the higher driving force which led to decrease of mass transfer resistance.

کلیدواژه ها

nanocomposite, Zn ions, column, effluent, breakthrough

مقالات مرتبط جدید

اطلاعات بیشتر در مورد COI

COI مخفف عبارت CIVILICA Object Identifier به معنی شناسه سیویلیکا برای اسناد است. COI کدی است که مطابق محل انتشار، به مقالات کنفرانسها و ژورنالهای داخل کشور به هنگام نمایه سازی بر روی پایگاه استنادی سیویلیکا اختصاص می یابد.

کد COI به مفهوم کد ملی اسناد نمایه شده در سیویلیکا است و کدی یکتا و ثابت است و به همین دلیل همواره قابلیت استناد و پیگیری دارد.