CO۲ Capture Exploration on Potassium Hydroxide Employing Response Surface Methodology, Isotherm and Kinetic Models

  • سال انتشار: 1399
  • محل انتشار: Iranian Journal of Chemistry and Chemical Engineering، دوره: 39، شماره: 5
  • کد COI اختصاصی: JR_IJCCE-39-5_021
  • زبان مقاله: انگلیسی
  • تعداد مشاهده: 65
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نویسندگان

Mahsa Saeidi

Department of Chemistry, Faculty of Science, North Tehran Branch, Islamic Azad University, Tehran, I.R. IRAN

Ahad Ghaemi

School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, P.O. Box: ۱۶۷۶۵-۱۶۳, Tehran, I.R. IRAN

Kambiz Tahvildari

Department of Chemistry, Faculty of Science, North Tehran Branch, Islamic Azad University, Tehran, I.R. IRAN

چکیده

In this research, KOH has been evaluated as a solid adsorbent for carbon dioxide (CO۲) capture. The effect of pressure, temperature, and KOH loading on CO۲ adsorption in a fixed-bed reactor were investigated. Response Surface Methodology (RSM) based on the central composite design (CCD) was used to evaluate the effects of operating parameters on adsorption capacity in order to achieve the optimum conditions. The experimental values of the responses were in decent agreement with the predicted result of regression models. Techniques such as Fourier Transform InfraRed (FT-IR) spectroscopy and X-ray diffraction (XRD) were used to study the consider KOH sorbent. The results show that CO۲ adsorption is improved with the loading of ۰.۵ g of KOH. The maximum CO۲ adsorption capacity was acquired for KOH at temperature ۴۵°C and pressure ۶ bars. The Freundlich model was found to be the best for fitting the adsorption of CO۲ owing to the closeness of the R۲ to unity. Furthermore, the kinetic study specified that the first-order model is well-fitted with the experimental data. Overall, the very high surface area of KOH adsorbent makes this adsorbent new promising material for CO۲ capture.

کلیدواژه ها

CO۲ Adsorption, KOH sorbents, Response surface methodology (RSM), Isotherm, Kinetics

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