Preparation and Thermophysical Properties of Ternary Eutectic Composite PCM for Thermal Energy Storage Applications

  • سال انتشار: 1403
  • محل انتشار: Iranian Journal of Chemistry and Chemical Engineering، دوره: 43، شماره: 1
  • کد COI اختصاصی: JR_IJCCE-43-1_015
  • زبان مقاله: انگلیسی
  • تعداد مشاهده: 74
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نویسندگان

Sureshkumar Kanchipuram Ramalingam

Department of Mechanical Engineering, Easwari Engineering College, Ramapuram, Chennai, INDIA

K. Gopi Kannan

Department of Mechanical Engineering, Indian Institute of Technology (ISM) Dhanbad, INDIA

Ahmad Rifqi Muchtar

Institute of Technology Bandung, Department of Engineering Physics, Bandung, INDONESIA

Sathyanarayanan Seetharaman

Department of Mechanical Engineering, Easwari Engineering College, Ramapuram, Chennai, INDIA

Dhayalini Bala

Assistant Manager, L&T construction Research and Testing center, Chennai, INDIA

Arun Balaji Subramanian

Nanoampere Materials Private Ltd., Chennai, INDIA

Karthick Velu

Centre for Ocean Research (DST-FIST) (MoES-ESTC cell), Sathyabama Institute of Science and Technology, Jeppiaar Nagar, Chennai, INDIA

Parameshwaran Rajagopalan

Department of Mechanical Engineering, Birla Institute of Technology and Science-Pilani, Hyderabad Campus, INDIA

Kalaiselvam S.

Department of Applied Science and Technology, Anna University, Chennai, INDIA

چکیده

In this study, graphene oxide (GO) particles were integrated into a ternary eutectic mixture of capric-lauric-myristic acid (CA-LA-MA) to form a composite material (CA-LA-MA/GO). The GO particles were synthesized using the modified Hummers method, and their size, shape, and morphology were confirmed through XRD and SEM analyses. The ternary mixture was prepared based on theoretically calculated mass ratios and validated using DSC. FT-IR analysis was employed to verify the physical interactions among the precursor components. Notably, the CA-LA-MA/GO composite exhibited thermal decomposition only above ۱۲۵°C. The phase change temperature demonstrated consistent behavior after the addition of GO, even after undergoing ۱۰۰۰ thermal cycles. Following these cycles, the composite PCM showed a decrease of ۵.۰۸% and ۳.۸۳% in freezing and melting latent heat, respectively. The thermal conductivity of the composite increased by ۳۶% due to the incorporation of GO, as confirmed by the accelerated melting and freezing processes. Based on these comprehensive findings, it can be concluded that the prepared CA-LA-MA/GO ternary eutectic composite holds great promise for applications such as low-temperature thermal energy storage, thermal energy conservation and management in buildings, and other potential fields.

کلیدواژه ها

Ternary eutectic PCM, Graphene oxide, Thermal properties, Building thermal management, Thermal Energy Storage

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