The enhancement in dye removal and antifouling capability of PES nanofiltration membrane modified with fumarate-alumoxane nanoparticles

  • سال انتشار: 1402
  • محل انتشار: دوفصلنامه تحقیقات کاربردی در آب و فاضلاب، دوره: 10، شماره: 2
  • کد COI اختصاصی: JR_ARWW-10-2_009
  • زبان مقاله: انگلیسی
  • تعداد مشاهده: 151
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نویسندگان

Golshan Moradi

CFD Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University, Kermanshah, Iran.

Sirus Zinadini

Environmental Research Center, Department of Applied Chemistry, Razi University, Kermanshah, Iran.

Masoud Rahimi

CFD Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University, Kermanshah, Iran.

چکیده

Fumarate-alumoxane nanoparticles (Fum-ANPs) incorporated PES nanofiltration membrane was fabricated via phase inversion to achieve favorable performance as the enhancement in the dye removal and antifouling capacity. FTIR spectra of the Fum-ANPs revealed that the carboxylate and hydroxyl functional groups were created on the surface of Fum-ANPs. The strong affinity of Fum-ANPs functional groups with water molecules made the membrane surface more hydrophilic. Hence, the modified membrane sample had a higher pure water flux than the bare one. Zeta potential data showed that the Fum-ANPs blended PES membrane was negatively charged at a pH value of ۶, which is favorable for negatively charged solute rejection. The antifouling behavior of the membranes was analyzed using powder milk solution (۸ g/L) in a dead-end filtration system. The obtained results demonstrated that the introduction of Fum-ANPs in the membrane matrix ameliorated the antifouling behavior of the resulting membrane. To further study the performance of the Fum-ANPs incorporated PES membrane, removal of Direct red ۱۶ dye was tested. The removal efficiency of Direct red ۱۶ with the Fum-ANPs blended PES membrane was ۹۹% while it was ۸۸.۲% for the bare membrane sample.

کلیدواژه ها

Nanofiltration, Polyethersulfone, Antifouling, Fumarate-Alumoxane nanoparticles, Dye removal

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