Ce-promoted Co/Al۲O۳ catalysts for Fischer–Tropsch synthesis: CatalyticPerformance of Co-Catalysts
- سال انتشار: 1402
- محل انتشار: اولین همایش ملی جاذب ها و کاتالیست های صنعتی
- کد COI اختصاصی: IDCCONF01_051
- زبان مقاله: انگلیسی
- تعداد مشاهده: 60
نویسندگان
Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, Zahedan, Iran
Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, Zahedan, Iran
Faculty of Industry & Mining (Khash), University of Sistan and Baluchestan, Zahedan, Iran
چکیده
A series of supports were synthesized using two methods of sol-gel and oil-drop. In this work, thesimultaneous effects of P۱۲۳ surfactant, promoters (cerium, zirconium, and boron), and ethanol solventon catalytic activity for the Fischer-Tropsch Synthesis (FTS) were studied. Cobalt catalysts wereprepared using the incipient wetness impregnation method on γ-alumina granules for FTS in a fixed-bedreactor. All the prepared granules Co catalysts were characterized using BET and XRD techniques. TheFTS operation condition was carried out at T=۵۰۳K, P=۱۵ bar, H۲/CO = ۲, and space velocity ۵.۱ NL·g−۱·h−۱. Our results clearly showed that the catalytic evaluation of the Co catalysts supported on γ-alumina,concerning, for, to the activity and selectivity of C۵+ products was increased by the addition of surfactantand promoters in FTS. Also, the Co catalysts supported with γ-alumina P۱۲۳ surfactant were more activethan the Co catalysts supported with γ-alumina. In addition, the morphologies of the γ-alumina supportedgranules were changed by surfactant and promoters. Meanwhile, the addition the simultaneous of P۱۲۳surfactant and Ce promoter with ethanol solvent remarkably influenced the improvement of activity,selectivity, and stability of the catalyst as well.کلیدواژه ها
sol–gel, P۱۲۳ surfactant, γ-alumina granules, Cobalt catalyst, Fischer -Tropsch synthesis,Anderson–Schulz–Flory (ASF) plot.مقالات مرتبط جدید
- Nanoclay composites as efficient nanocatalysts for energy applications
- Oxidation of sulfides by Cu+/g-C۳N۴ as catalyst under visible lightirradiation
- Investigation of molybdenum and cerium source in an improved catalystfor the dehydrogenation of ethylbenzene to styrene
- An Overview of Electrochemical Desulfurization Technology
- A brief review of the types of adsorbents and the effect of surfacemodification on the adsorption capacity enhancing
اطلاعات بیشتر در مورد COI
COI مخفف عبارت CIVILICA Object Identifier به معنی شناسه سیویلیکا برای اسناد است. COI کدی است که مطابق محل انتشار، به مقالات کنفرانسها و ژورنالهای داخل کشور به هنگام نمایه سازی بر روی پایگاه استنادی سیویلیکا اختصاص می یابد.
کد COI به مفهوم کد ملی اسناد نمایه شده در سیویلیکا است و کدی یکتا و ثابت است و به همین دلیل همواره قابلیت استناد و پیگیری دارد.