Is synthesizing a Cu۳۵Co۳۵Ni۲۰Ti۵Al۵ high-entropy alloy beyond the rules of solid-solution formation?
- سال انتشار: 1402
- محل انتشار: فصلنامه سنتز و تفجوشی، دوره: 3، شماره: 4
- کد COI اختصاصی: JR_SYNSINT-3-4_002
- زبان مقاله: انگلیسی
- تعداد مشاهده: 49
نویسندگان
چکیده
In this research, an attempt was made to produce multi-component nanocrystalline Cu۳۵Co۳۵Ni۲۰Ti۵Al۵ alloy by mechanical alloying. To produce this high-entropy alloy, the primary powders were milled for ۴۰ h and characterized by XRD, SEM, EDS, and DSC analyses. The milling process has reduced the size of the crystallites to the nanometer scale and a nanostructured multicomponent powder with a crystallite size of ۲۹ nm was obtained. According to the XRD patterns and EDS maps of the milled powder for the longest time, aluminum and copper were homogeneously distributed, cobalt had a less homogeneous distribution than these two elements, but nickel and titanium remained in concentrated spots. Finally, thermodynamic calculations were done to clarify the reason for the impossibility of forming a solid solution for the synthesis of the Cu۳۵Co۳۵Ni۲۰Ti۵Al۵ high-entropy alloy.In this research, an attempt was made to produce multi-component nanocrystalline Cu۳۵Co۳۵Ni۲۰Ti۵Al۵ alloy by mechanical alloying. To produce this high-entropy alloy, the primary powders were milled for ۴۰ h and characterized by XRD, SEM, EDS, and DSC analyses. The milling process has reduced the size of the crystallites to the nanometer scale and a nanostructured multicomponent powder with a crystallite size of ۲۹ nm was obtained. According to the XRD patterns and EDS maps of the milled powder for the longest time, aluminum and copper were homogeneously distributed, cobalt had a less homogeneous distribution than these two elements, but nickel and titanium remained in concentrated spots. Finally, thermodynamic calculations were done to clarify the reason for the impossibility of forming a solid solution for the synthesis of the Cu۳۵Co۳۵Ni۲۰Ti۵Al۵ high-entropy alloy.کلیدواژه ها
Mechanical alloying, High-entropy alloys, Solid solution, Unsuccessful synthesis, Thermodynamicsاطلاعات بیشتر در مورد COI
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