Enhancement of Efficiency of Water Removal from Bangestan Crude Oil by Silica Nanoparticles Using Imidazolium-based Ionic Liquids

  • سال انتشار: 1401
  • محل انتشار: مجله علوم و فن آوری نفت، دوره: 12، شماره: 2
  • کد COI اختصاصی: JR_JPSTR-12-2_006
  • زبان مقاله: انگلیسی
  • تعداد مشاهده: 83
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نویسندگان

Ali Mehdizadeh

Chemical, Polymeric, and Petrochemical Research Division, Faculty of Upstream Research and Development, Research Institute of Petroleum Industry IRPI, Tehran, Iran

Fakhrotolou Masoumi

Chemical, Polymeric, and Petrochemical Research Division, Faculty of Upstream Research and Development, Research Institute of Petroleum Industry IRPI, Tehran, Iran

Amir Nasser Ahmadi

Chemical, Polymeric, and Petrochemical Research Division, Faculty of Upstream Research and Development, Research Institute of Petroleum Industry IRPI, Tehran, Iran

Marzieh Shekarriz

Chemical, Polymeric, and Petrochemical Research Division, Faculty of Upstream Research and Development, Research Institute of Petroleum Industry IRPI, Tehran, Iran

Shahriar Ghamami

Department of Chemistry, Imam Khomeini International University, Qazvin, Iran

چکیده

The effect of coating silica nanoparticles by several ۱-alkyl-۳-methylimidazolium hexafluorophosphate ionic liquids of [Rmim][PF۶] general formula (R= C۱۰, C۱۲, and C۱۴) on the water removal efficiency of silica nanoparticles from crude oil emulsions have been studied in this study. The ionic liquids have been prepared and characterized by comparing their ۱HNMR and FT-IR spectra with those reported in the literature. In addition, the effects of factors including cation alkyl chain length and concentration of the ionic liquids prepared on the water separation efficiency of the demulsifier have also been investigated to determine the optimal values for the chain length and concentration of the ionic liquid. [C۱۴mim][PF۶] ionic liquid at a concentration of ۱۲۰۰ ppm was shown to be the most efficient ionic liquid among the ionic liquids studied. The water separation efficiency achieved using coated nanosilica under optimal conditions was ۹۳.۳%.

کلیدواژه ها

Ionic Liquids, Demulsification, Crude Oil, Silica Nanoparticles

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