Carbon dioxide (CO۲) adsorption by HKUST-۱ (MOF-۱۹۹)
- سال انتشار: 1402
- محل انتشار: بیست و دومین کنفرانس شیمی معدنی ایران
- کد COI اختصاصی: IICC22_191
- زبان مقاله: انگلیسی
- تعداد مشاهده: 63
نویسندگان
Department of Thermokinetic and catalyst, Faculty of Chemical Engineer, Babol NoshirvaniUniversity of Technology, Babol, Iran
Department of Thermokinetic and catalyst, Faculty of Chemical Engineer, Babol NoshirvaniUniversity of Technology, Babol, Iran
Department of Chemistry, Faculty of Science, Babol Noshirvani University of Technology, Babol,Iran
چکیده
One approach to mitigating global warming is the capture and storage of CO۲ as the majorgreenhouse gas [۱]. Materials that are commonly used for CO۲ adsorption include activated carbon,zeolites [۲], and metal-organic frameworks (MOFs) [۳]. HKUST-۱ (also known as MOF-۱۹۹) is awell-known metal-organic framework that has been extensively studied for its potentialapplications in gas storage and separation. In this work, HKUST-۱ was investigated as anadsorbent for CO۲. HKUST-۱was synthesized using the hydrothermal method and its chemicalproperties were investigated using various characterization techniques including XRD, FTIR,FESEM, BET, and TGA. It was shown that HKUST-۱ has a crystalline structure with a surfacearea of over ۱۷۰۴ m۲/g, and a petal-shaped molecular structure. It also showed thermal stability upto a temperature of ۳۶۶°C. The results of CO۲ adsorption showed that the amount of carbon dioxideadsorption by HKUST-۱ at ۲۰°C, ۳۰°C and ۴۰°C and ۱bar was ۳.۷۸۸, ۳.۴۱۷, and ۳.۰۸۸mmol/g,respectively. However, in ۱۰ bar and the same temperatures, its adsorbtion improved to ۹.۰۹۰,۸.۷۸۲, and ۷.۷۲۴ mmol/g, respectively. Therefore, it can be concluded that the amount of carbondioxide adsorption enhanced with increasing CO۲ pressure and decreases when temperatureincreases. Therefore, HKUST-۱ could be suggested as a promissing CO۲ adsorbent at moderatetemperatures.کلیدواژه ها
CO۲ adsorption, metal organic frameworks, HKUST-۱, CO۲ Capture, greenhouse gasاطلاعات بیشتر در مورد COI
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