Photocatalytic removal of ciprofloxacin antibiotic from aqueous medium by applying AgI/Ag۲O nanocomposite: Activity test, reaction kinetics, and catalyst reusability

  • سال انتشار: 1401
  • محل انتشار: مجله مدیریت و مهندسی بهداشت محیط، دوره: 9، شماره: 3
  • کد COI اختصاصی: JR_EHEM-9-3_012
  • زبان مقاله: انگلیسی
  • تعداد مشاهده: 141
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نویسندگان

Mehdi Ahmadmoazzam

Department of Environmental Health Engineering, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran

Afshin Takdastan

Corresponding author: Department of Environmental Health Engineering, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran

Abdolkazem Neisi

Department of Environmental Health Engineering, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran

Mehdi Ahmadi

Department of Environmental Health Engineering, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran

Ali Babaei

Department of Environmental Health Engineering, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran

Sahand Jorfi

Department of Environmental Health Engineering, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran

چکیده

Background: This study examined the removal of ciprofloxacin (CIP), which is a very widely used antibiotic, from an aqueous medium by applying AgI/Ag۲O photocatalyst under visible light radiation. Methods: AgI/Ag۲O was synthesized conveniently by applying a two-stage precipitation method. The synthesized compound was characterized by X-ray powder diffraction (XRD), FE- field emission scanning electron microscopy (FE-SEM), energy dispersive x-ray (EDX), and UV-Vis spectrophotometry. Different parameters including initial pH of the solution, initial CIP concentration, reaction kinetics, and catalyst reusability were investigated. Results: Concurrent use of AgI and Ag۲O caused improved photocatalytic properties in the presence of UV light. The pH and initial concentration of CIP affected the process efficiency; ۹۵% efficiency was achieved within ۱۰۰ min at pH ۹. Furthermore, the process efficiency was still maintained over ۹۰% after four consecutive cycles. Conclusion: The photocatalytic degradation process using AgI/Ag۲O nanocomposite under visible light radiation is a suitable method for removing CIP from aqueous media due to its high efficiency and stability.

کلیدواژه ها

Ciprofloxacin, Nanocomposites, Photolysis, Catalysis, Antibiotic, Aqueous medium

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