Synthesis of porous CdO sheet-like nanostructure based on soft template model and its application in dye pollutants adsorption

سال انتشار: 1395
محل انتشار: مجله بین المللی ابعاد نانو، دوره: 7، شماره: 2
کد COI اختصاصی: JR_IJND-7-2_007
زبان مقاله: انگلیسی
تعداد مشاهده: 115

نویسندگان

Research Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology, ۱۶۸۴۶-۱۳۱۱۴, Tehran, Iran.

Mina Imani

Research Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology, ۱۶۸۴۶-۱۳۱۱۴, Tehran, Iran.

چکیده

In this work, the synthesis of porous structure of cadmium oxide with multilayered sheet-like morphology in nano-meter size using adipic acid as soft template by solvothermal/thermal decomposition process is reported. Chemical analyses exhibited that the formation of porous sheet-like structure is originated from bidentate coordination mode of adipate units to Cd-center. It was found that the change of reaction conditions can vary final morphology of product due to the different coordination modes of adipate units. The structural and morphological characterizations of product were discussed in detail. Brunauer-Emmett-Teller (BET) analysis indicated a specific surface area of ۵۲.۰۸ m۲g-۱ with pore size distribution centered at ۱۱.۷ nm for prepared CdO sheet-like nanostructure. The capability of the as prepared product for adsorption of dye pollutants from aqueous solution was also studied. The results showed a maximum adsorption capacity (qmax) of ۵۰۰ mg g−۱ for adsorption of Congo Red (CR) dye in water revealing a superior ability of this product for adsorption of dye pollutants.

کلیدواژه ها

Adsorption, CdO, nanostructure, Soft template, Solvothermal process

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