Malligavathy Rajakumar - Manonmaniam Sundaranar University, Tirunelveli
Pathinettam Padiyan - Manonmaniam Sundaranar University

We report the significance of hydrothermal temperature of TiO۲ nanoparticles on the crystallinity, band gap and the photocatalytic degradation of congo red dye. These nanoparticles are synthesized by hydrothermal method at ۱۲۰ ˚C, ۱۴۰ ˚C and ۱۶۰ ˚C. The anatase phases of the samples are confirmed from the X-ray diffraction pattern and the surface morphology of the sample is visualized in a high-resolution scanning electron microscope. The observed optical band gap value supported that TiO۲ nanoparticles can be used as a visible light photocatalytic which is also in agreement with the photoluminescence spectrum. TiO۲ nanoparticles prepared at ۱۶۰ ˚C degrades ۹۸.۳ % of congo red in ۹۰ min and the kinetics of degradation is analysed using both pseudo first (Langmuir Hinshelwood model) and second order equations. It is found that the pseudo second order (Blanchard) equation fits well for the whole range of degradation with the correlation coefficient of ۰.۹۹۹۹.

Metal oxides, Structural properties, Optical properties, pseudo first and second order equations