The oretical Study of Free Activa tion Ener gies of Electron Transfer Process in Nano-co mplexesofmeta and para-tetra Bis ۳,۴- tetra phenyl ethylen s withFulleren es

In this study, the number of c arbon atoms in fulleren es was used as descriptors to establish a good relationship between t he structure of [m,p-di-phenyl-methyldene-fluorscent].[Cn] and Fullerenes Cn (n= ۶۰, ۷۰, ۷۶, ۸۲ and ۸۶). The first to f ourth free activation energies and kinetic rate c onstant of the electron-t ransfer, ¨Get(n)# and ket(n), n=۱-۴ ,res pectively were calculat ed for the complexes of and Fulleren es[m,p-Bis ۳,۴-tetra phe nyl ethylenes].[Cn].

کلیدواژه ها:

ele ctron-transfer ، electro chimecal oxidation an d reduction ، electrochemical prope rties ، oxidation-potentia l.