Application of Polyethylene Glycol Grafted-CuO Nanoparticles in Solid Phase Extraction of Phthalate Esters in Baby Shampoo and Body Wash
- سال انتشار: 1400
- محل انتشار: دوفصلنامه ایرانی شیمی تجزیه، دوره: 8، شماره: 1
- کد COI اختصاصی: JR_IJAC-8-1_005
- زبان مقاله: انگلیسی
- تعداد مشاهده: 358
نویسندگان
Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad. Mashhad, Iran
Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad. Mashhad, Iran
Department of Chemistry, Payame Noor University, ۱۹۳۹۵-۴۶۹۷ Tehran, Iran
چکیده
This study considers identification and determination of phthalates esters in cosmetic samples. The dispersive solid phase extraction was used for extraction of analytes prior to high performance liquid chromatography analysis. The solid sorbent for extraction was polyethylene glycol grafted on cupric oxide nanoparticles (PEG-g-CuO-NPs). This sorbent was first synthesized and characterized by scanning electron microscopy (SEM), Energy-dispersive X-ray(EDX) and fourier-transform infrared spectroscopy (FT-IR) then efficiently applied for extraction of analytes. The extraction conditions like amount of sorbent, kind and volume of desorption solvent, extraction and desorption time, and pH of sample solution were optimized. The validation of method carried out under optimum conditions. Linear ranges were ۰.۰۰۵-۴ µgmL-۱ with the coefficient correlation (R۲) in the range of ۰.۹۹۱۴-۰.۹۹۶۲. The limits of detection (LODs) (۳S/N) were ۰.۰۰۲۵ to ۰.۰۰۵ µgmL-۱ and acceptable repeatability’s (RSDs below ۶.۴۵%, n=۵) obtained. Application of proposed method was investigated by extraction of phthalates in shampoo and body wash for babies which satisfaction results achieved.کلیدواژه ها
phthalate esters, HPLC, Baby shampoo, Body wash, polyethylene glycol grafted cupric oxide nano particlesاطلاعات بیشتر در مورد COI
COI مخفف عبارت CIVILICA Object Identifier به معنی شناسه سیویلیکا برای اسناد است. COI کدی است که مطابق محل انتشار، به مقالات کنفرانسها و ژورنالهای داخل کشور به هنگام نمایه سازی بر روی پایگاه استنادی سیویلیکا اختصاص می یابد.
کد COI به مفهوم کد ملی اسناد نمایه شده در سیویلیکا است و کدی یکتا و ثابت است و به همین دلیل همواره قابلیت استناد و پیگیری دارد.