Effective removal of cationic methylene blue and crystal violet dyes on a novel magnetic Fucus vesiculosus (brown algae)
محل انتشار: بیست و هفتمین کنفرانس شیمی آلی ایران
سال انتشار: 1398
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 146
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شناسه ملی سند علمی:
ISOC27_042
تاریخ نمایه سازی: 19 اسفند 1399
چکیده مقاله:
In this project, a new magnetic Fucus vesiculosus (m-FV) nanoparticle with a high adsorption capacity of cationic dyes was prepared. To achieve a high effective nanocomposite, Fucus vesiculosus (FV) modified using ultrasound and then, the magnetic property induced via in situ co-precipitation of iron ions in the presence of FV1. The produced m-FV examined to remove cationic methylene blue (MB) and crystal violet (CV) dyes from aqueous solutions. The effect of contact time revealed a fast removing of MB and CV, reaching equilibrium at 10 and 5 minutes, respectively. Adsorption process Kinetics modeled and the results presented the best fit of experimental data for pseudo-second-order (PSO) than that of pseudo-first-order (PFO) kinetic model in MB and CV adsorption processes2. Analyzing equilibrium isotherm data carried out using Langmuir and Freundlich models and the results revealed a better fitting to the Langmuir model for MB and CV adsorption processes. According to the Langmuir model, the maximum adsorption capacity of m-FV obtained 577 and 1062 mg.g-1 for MB and CV, respectively3. Easy recovery, good recyclability, pH and temperature-independent properties of m-FV nanoparticles, moreover than high adsorption capacity, could be employed as an effective and low-cost adsorbent in the removal of dye pollutions4.
کلیدواژه ها:
نویسندگان
Hessam Jafari
Polymer Research Laboratory, Department of Chemistry, College of Agriculture, University of Maragheh, Maragheh, Iran.
Bagher Kazemi
Department of Chemistry, Iran University of Science and Technology, Tehran ۱۶۸۴۶-۱۳۱۱۴, Iran.
Samira Alinavaz
Polymer Research Laboratory, Department of Chemistry, College of Agriculture, University of Maragheh, Maragheh, Iran.
Gholamreza Mahdavinia
Polymer Research Laboratory, Department of Chemistry, College of Agriculture, University of Maragheh, Maragheh, Iran.