Synthesis and characterization of NiS2 nanoparticles ingrained into the sulfur-doped carbon nitride nanosheets for application as efficient photocatalysts
سال انتشار: 1399
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 266
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شناسه ملی سند علمی:
BCBCN03_016
تاریخ نمایه سازی: 7 بهمن 1399
چکیده مقاله:
A one-step, simple and low-cost strategy toward synthesis of NiS2/S-doped g-C3N4 (NiS2/CNS) composites was successfully accomplished. The hybrid photocatalyst materials with different amounts of NiS2 nanoparticles (NPs) were successfully in situ synthesized via thermal condensation of a mixture containing thiourea and nickel(II) nitrate. The hybrid materials were characterized by XRD, TEM, FT-IR, BET, XPS, PL and DRS analyses. Interestingly, thiourea showed two very important roles: (1) thiourea not only acted as a precursor to in situ produce the sulphur-doped carbon nitride materials, but also (2) sulphur atmosphere originated from polycondensation of thiourea provided a sulphur source for in situ production of NiS2 nanoparticles as a non-noble metal sulphide on the CNS sheets during the synthesis. The XRD patterns of the CNS exhibited two peaks near 13.1 and 27.4°, corresponding to diffractions from (100) and (002) planes, respectively. The sharp peak at 27.4° was attributed to the interplanar stacking units of aromatic system whereas the weak peak at 13.1° was associated to in-plane structural packing motif
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نویسندگان
Zahra Mirzaeifard
Department of Chemistry, Amirkabir University of Technology (Tehran Polytechnic), P.O.Box:۱۵۸۷۵-۴۴۱۳, Tehran, Iran
Zahra Shariatinia
Department of Chemistry, Amirkabir University of Technology (Tehran Polytechnic), P.O.Box:۱۵۸۷۵-۴۴۱۳, Tehran, Iran
Milad Jourshabani
Department of Chemistry, Amirkabir University of Technology (Tehran Polytechnic), P.O.Box:۱۵۸۷۵-۴۴۱۳, Tehran, Iran